Polymer Surface Functionalisation And Grafting By A Simple And Inexpensive Method

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A new, simple approach to confer permanent antimicrobial

A new, simple approach to confer permanent antimicrobial properties to hydroxylated surfaces by surface functionalizationw Othman Bouloussa,a Francis Rondelezab and Vincent Semetey*ab Received (in

Covalent Grafting of a Patterned, Hyperbranched Polymer onto

polymer grafting steps2,3 used to prepare PAA patterns on plastic surfaces. Recently, Whitesides1,6,7 and others8-10 described í-CP, which is a soft lithographic method used to transfer patterned monolayers of alkanethiols,11,12 alkanephosphonic acids,13 and alkylsilanes14 onto Au, Ag, Al, glass, and Si/SiO2 substrates. í-CP has also

Glycosylated gold nanoparticle libraries for label-free

label-free, easy and inexpensive sensors for the analysis of carbohydrate protein interactions is highly desirable. The current best methods for this are interfe rometry, quartz crystal micro-balance (QCM) and surface plasmon resonance (SPR). However, all three of these require infrastructure and are still relatively low-

CHAPTER FIVE - Research Commons

One aim of this study was to develop a simple and inexpensive method to functionalise the prepared microcapsules. Grafting trials were done to identify an ideal polymer and to save time and materials before further developing the microcapsule structure. Chemical methods, with many advantages for surface

Carbon-Based Polymer Nanocomposites for High-Performance

Apr 10, 2020 percentages via a simple solution casting method, and the nanocomposites were analyzed by di erent techniques to obtain information on the e ect of the HDI-GO level of functionalization and percentage on the nanocomposite properties. The best properties were obtained for nanocomposites with HDI-GO contents in the range of 2 5 wt %.

Synthesis, Characterization of Cellulose Grafted N-Oxide

Preparation of chemically modified polymer surfaces with controllable structures is an area of current research, having both theoretical and practical interest [1]. The objective is to devise mild techniques of primary surface functionalization with a high degree of chemo- and topological selectivity. The primary functional groups on

This is an author http://oatao.univ-toulouse.fr/24533

Surface functionalization of plasticized chitosan films through PNIPAM grafting via UV and plasma graft polymerization G. Conzatti8, S. Chamarya, N. De Geyterh, S. Cavaliea, R Morenth, A. Tourrettea,* a Universlti de Tculouse, ClRIMAT, UPS-INPT-CNRS, Faculté de l'hamruk, 118 Routt de Narbonne, 31062 Tculouse œder 4, Pranœ

PAPER OPEN ACCESS -nanoparticles Coated Forward Osmosis

Feb 18, 2020 grafting macromolecules preparing antifouling surfaces by functionalization with photocatalytic nanoparticles and carbon-based nanomaterials and using biocidal Nanoparticles whichever consolidated into the support layer or connected to the surface of the TFC membranes [3].

Sensing and Bio-Sensing Research

immobilization.It is a known fact that paper surface is slightly negative charged, which is partly caused by the presence of carboxyl groups [9, 18]. To further evaluate this possibility, we performed direct enzyme immobilization on filter paper without the NHS/EDC activation. Once eliminating the activation step, paper surface would only have

Extremely durable biofouling-resistant metallic surfaces

simple, non-hazardous and inexpensive method to prepare durable, non-wetting steel surfaces with uncompromised mechanical properties, which repel a variety of contaminants, has immediate relevance in applications that suffer from the above-mentioned issues16. In recent decades, superhydrophobic surfaces (SHS)17, which

Nanoscale - Royal Society of Chemistry

opportunities for grafting polymer-Py on the RGO surface during the conversion of CCG. Thirdly, the synthesized polymer-FG has a comparable grafting ratio (~2 chains per 1000 carbon) to covalently functionalized graphene; therefore the described method facilitates the facile fabrication of

Applied Surface Science

order to increase the number of surface active sites on these carbon nanostructures, they are usually subjected to various post-treatment procedures including oxidation, polymer coating and grafting [11 14]. In contrast to other carbonaceous materials, ultrathin carbon nanosheets including graphene [15] are usually oxygenated, bea-ring

Materials and Design

columns (static method) the process requires heavy equipment and the regeneration can be hard. On the other hand, if the materials are used in dispersion (dynamic method), the removal is an additional op-eration step. Moreover, if the active removal moiety is a sugar deriva-tive, the synthesis can be very challenging.

Cold atmospheric plasma (CAP) surface nanomodified 3D printed

materials) in a quick and an inexpensive manner and, thus, should be further studied. Statement of Significance Three-dimensional (3D) printing is a new fabrication method for tissue engineering which can precisely control scaffold architecture at the micron-scale. Although their success is related to their ability to

Electrophoresis 24, 1 Fabrication of porous polymer monoliths

plastic polymer materials together with inexpensive dry techniques such as injectionmolding or hot embossing is desired. Consequently, the development of polymeric substrates for microfluidic devices has become a priority. In applications that largely rely on interactions with the solid surface such as chromatographic separations, het-

Article Enantioselective Transamination in Continuous Flow

inexpensive. Moreover, its surface can be easily functionalized to allow the subsequent anchoring of enzymes [23]. For example, grafting amine groups on silica surface using (3-aminopropyl)triethoxysilane (APTES) favors electrostatic attraction between the silica carrier and the enzymes [24,25].

Modulation of the organic heterojunctions behavior, from

6-cluster, was synthesized via the hydrothermal method by using aminopyridinium (APy)+ cations as the hybrid material, and characterized by FT-IR spectrometry and thermal analysis. A simple and reliable procedure was implemented for the synthesis of new composite materials obtained by the covalent grafting of (APy) 6 [H 2 W 12 O 40


The third is a modification of cellulose membranes by polymer grafting. Unlike the two previous processes, this technique was developed in order to increase the functionality of the non-sensing cellulose parts of paper-based devices. Yet, it may be employed as another functionalization method for covalent antibody immobilization on cellulose.

Elsevier Editorial System(tm) for Carbohydrate Polymers

One advantage of LbL technique is that the process is inexpensive, relatively fast and simple, does not require sophisticated equipment and precise stoichiometry comparing with other functionalization techniques for textiles. Moreover, surface functionality can be controlled

Article Enantioselective Transamination in Continuous Flow

the APTES concentration used in the functionalization step. ATA-117 external surface also exhibits six lysine residues (Figure S3). In method (c), glutaraldehyde was used as a coupling agent [29,32] to promote the covalent grafting between the amino functions on the APTES-functionalized Si(HIPE) and the lysine residues of the enzyme

Removal of Mercury (II) by EDTA-Functionalized Magnetic

Oct 29, 2019 When the particle diameter (d) is smaller, the specific surface area is higher, which promotes the di usion of particles in the solution, therefore, it is preferred to use a small size adsorbent [24]. The preparation of iron-based materials (such as CoFe2O4) in particular is simple and inexpensive,

ResistanceSwitchable Graphene OxidePolymer Nanocomposites for

Since 2005, polymer memories have been proposed to revolutionize electrical applications by providing extremely inexpensive, lightweight, and transparent As the thinnest material ever known in the universe, graphene has attracted a tremendous amount of attention in recent years. To switch graphene ON and OFF for memory devices,

Journal of Materials Chemistry B

label-free, easy and inexpensive sensors for the analysis of carbohydrate protein interactions is highly desirable. The current best methods for this are interfe rometry, quartz crystal micro-balance (QCM) and surface plasmon resonance (SPR). However, all three of these require infrastructure and are still relatively low-

Improved antifouling properties and selective

properties and appropriate surface functionalities are seldom readily available. Therefore, surface modification of materials that demonstrate otherwise potential properties, such as stainless steel (SS), is often preferable 2,4. For example, through covalent coupling reactions and polymer grafting, otherwise biologically challenging materials

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25 silanol groups. The activated surface is then functionalized with amine groups as anchors for further grafting with a hydrophilic polymer to prevent protein adsorption. (3-Aminopropyl)triethoxysilane (APTES) and (3-aminopropyl)trimethoxysilane (APTMS) are organosilanes that 30 are commonly used to introduce amine groups for further protein


reasons, surface modification techniques can transform these inexpensive materials into valuable finished products have become an important part of the plastics industry. In recent years, many advances have been made in developing surface treatments to alter the chemical and physical properties of polymer surface without affecting bulk

Polymer grafted multiwalled carbon nanotubes via facile in

polymerisation conditions in the present method was similar to those in the range of 12 16% reported. However, the present method was simple, convenient, and inexpensive. 4. Conclusions In summary, a facile and effective method was developed for the grafting polymers onto the pristine MWCNTs via the in situ solution free radical

Cellulose Schi Base as a Bio-based Polymer Ligand: Extraction

in the heavy metal adsorption from wastewater. A simple, efficient, and new method have been developed for the extraction of cellulose from dried stem powder Sa ower (Carthamus tinctorius L.). To prepare an e cient new high surface biosorbent for metal ions, the extracted cellulose was cross-linked, periodate oxidized, and then functionalized

Journal of Materials Chemistry B

Surface-functionalization of PDMS for potential micro-bioreactor and embryonic stem cell culture applications Fatemeh Sarvi,a Zhilian Yue,bc Kerry Hourigan,a Mark C. Thompsona and Peggy P. Y. Chan*cd This study presents a novel and inexpensive method to prepare a disposable micro-bioreactor for stem cell expansion.

Superwettable PVDF/PVDF g PEGMA Ultrafiltration Membranes

strategies to realize surface customization of PVDF mem-branes; among the effective methods currently applied are surface coating, surface grafting, and blending.7−11 Blending is the most common method due to its simple operation, achieved material stability, and adequate modification results.12 Among the materials used for blending with PVDF,

Synthesis, characterization and melt functionalization of

Melt grafting is a way to minimize the undesired properties by introducing additional functions in a polymer. By using the melt functionalization method, functional compounds are chemically grafted onto the backbone of polyolefins to make them environment friendly, i.e., to make them active towards the bio-degradation process.

Rapid Evaluation of Surface Properties of Medical Tubing for

If we want to create a surface with specific properties through adhesion of a substance or through chemical grafting, this process has to be carried out while the surface to be modified has enough surface free energy to allow the reaction to occur. For example, we may plasma treat a polymer to promote adhesion of a coating. A plasma treated surface


Jun 15, 2019 A gold surface was first of all patterned by silica nanospheres, then a cysteamine SAM was grafted onto the free surface; acid chloride-functionalized SWCNTs were grafted onto the amine-modified distal end of the SAM by electrophoretic deposition. Similar vertically aligned SWCNT arrays were also fabricated on a silicon surface via a

Functionalisation of textiles by inorganic sol gel coatings

polymer melt or polymer solution before spinning. The Chemical grafting of additives on the fibre surface directly or by means of linkers. This effective method yields excellent