Classical Theory Of Homogeneous Nucleation In Superheated Liquids And Its Experimental Verification

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Nanosecond Near-Spinodal Homogeneous Boiling of Water

homogeneous nuclea-tion (HN) of separate vapor bubbles merges with coherent spinodal decomposition (SD) of the corresponding superheated liquid correlated over a long scale [1,2]. Classical HN theory predicts metastability of the bulk superheated liquid with respect to non-interacting finite fluctuations of its local entropy S. and volume V